Gas scrubber system and method

ABSTRACT

A system for treating a biogas stream is described. The system includes a venturi device in communication with a biogas stream source and an influent water source to combine the biogas stream and the influent water to produce a gas-water effluent. The system also includes a degas separator in communication with the venturi device for receipt of the gas-water effluent to produce a relatively low solubility gas effluent and a relatively high solubility gas-water mixture effluent. In addition, the system includes a gas-water pressure release valve in communication with the degas separator to control release of the relatively low solubility gas effluent and a discharge pressure control valve in communication with the degas separator to control release of the relatively high solubility gas-water mixture effluent.

CROSS REFERENCE TO RELATED APPLICATION

This application is a divisional of, and claims priority to, U.S. patentapplication Ser. No. 14/121,619, filed on Sep. 26, 2014, now U.S. Pat.No. 9,387,431, the entire contents of which are hereby incorporated byreference.

BACKGROUND OF THE INVENTION

This invention relates to systems and methods for removing unwantedelements from a gas stream. The new system and method treats a biogasstream that may be produced at facilities such as a municipal wastewatertreatment plants that have methane gas as well as other gases such ashydrogen sulfide H₂S, carbon dioxide CO₂ and other trace gases likesiloxanes.

Use of gas produced in wastewater treatment facilities has long been achallenge because of the mixture of gases in the biogas produced duringtreatment. Of particular interest have been natural gases such asmethane that can be recycled or used in cogeneration equipment or as avehicle fuel as a cost efficiency and for reduction in greenhouse gasgeneration. The burning or combustion of methane that may becontaminated with other gases such as carbon dioxide and hydrogensulfide has been increasingly regulated by air quality controlregulations. In some areas even the hydrogen sulfide must be removedfrom biogas produced during water treatment before the gas can be flaredor burned.

Current water treatment processes and methods may normally react biogaswith iron in iron sponge scrubbers to clean the gas. There are variouscommercially available methods of iron scrubbing processes; however,they rely on adsorption and reaction of the sulfide into an iron matrix.The matrix is regenerated by oxidation of the iron to ferric oxide andoxidation of the sulfide to elemental sulfur or sulfates. Discharge ofeffluents is back to the head of the treatment plant.

A more efficient method is required for biogas produced in wastewatertreatment in order to realize the benefit of use of combustible gas forcogeneration use in treatment facilities. The beneficial use of biogasgenerated in wastewater treatment depends on the cost to separate a gassuch as methane from the other gases present in order to obtain a highenergy gas stream similar to commercial gas.

SUMMARY OF THE INVENTION

The present invention is directed to systems and methods for removingunwanted elements from a gas stream. A biogas stream may be combinedwith a water stream influent in a venturi device to produce a gas-watermixture effluent. The gas-water mixture effluent is processed in a degasseparator to separate and produce a relatively low solubility gaseffluent and a relatively high solubility gas-water mixture effluent.The relatively high solubility gas-water mixture effluent is processedthrough a discharge pressure control valve based on a selected pressureto be maintained in said degas separator and then discharged or reused.

These and other features, aspects and advantages of the presentinvention will become better understood with reference to the followingdrawings, description and claims.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a functional diagram of a gas scrubbing processaccording to an embodiment of the invention;

FIG. 2 illustrates a functional diagram of a gas scrubbing process witha gas-water recycle process according to an embodiment of the invention.

DETAILED DESCRIPTION

The following detailed description represents the best currentlycontemplated modes for carrying out the invention. The description isnot to be taken in a limiting sense, but is made merely for the purposeof illustrating the general principles of the invention.

Referring to FIG. 1, a gas scrubbing process 10 receives a biogas 20from a wastewater treatment system 50. The wastewater treatment system50 may also serve as the source of a steady supply of water influent 22that may be under high pressure from the treatment wash water or plantwater system. This availability of water at water treatment plants is anasset that can be used to produce combustible gas such as methane gasusing an efficient method as compared to existing processes.

The gas scrubbing process 10 may mix the biogas 20 in the water influent22 in a venturi device 30. The gas-water mixture 24 produced may becommunicated to a degas separator 32 to separate low solubility gas 26such as methane gas from the gas-water mixture 24. The degas separator32 may produce low solubility gas 26 that is controlled at a gas-waterseparation device 34 such as a gas pressure release valve, and maydischarge a high solubility gas-water mixture 28 to be communicated to adrain 38 through a discharge pressure control valve 36.

Referring to FIG. 2, the gas scrubbing process 10 may also include agas-water return recycle process. The discharged high solubilitygas-water mixture 28 may be communicated to a water return vessel 40.Purge overflow gas-water may be discharged to the drain 38 and therecycle high solubility gas-water mixture 46 may be returned through apump 42 to the venturi device 30. In this gas scrubbing process 10,makeup water 44 may be introduced into the water return vessel 40 ratherthan supply water influent 22 being an influent directly into theventuri device 30.

The operation of the gas scrubbing system 10 separates methane gas fromother gases present in gas produced from anaerobic decomposition oforganic matter. The biogas 20 is introduced with pressurized water 22 inthe venturi device 30 and the mixed gas-water flow is maintained in thesystem 10 by a pressure control valve 36 at approximately 1 to 250 psi.The biogas 20 may be urged into the venturi device 30 by the vacuumcaused by the water 22 pressurized flow through the venturi device 30 orby biogas pressure flow of approximately −2 to +50 psi into the throator constriction of the venturi device 30. The water may be pressurizedto feed the venturi device 30 at pressures of approximately 10 to 500psi. The merging of the biogas and water flow causes the relatively highsoluble gases, for example, carbon dioxide, hydrogen sulfide andsiloxanes, to be dissolved in the water while the methane and otherrelatively lower soluble gases may be maintained in gas or undissolvedform. In experiments it was found the water pressure should be at least20 psi and the system 10 operated effectively at 30 to 40 psi of waterpressure. A water pressure above 250 to 500 psi caused increasing lossof methane gas to the gas-water mixture. The discharge pressure controlvalve 36 should be operated at as low a discharge pressure as iseffective/to scrub methane gas. The valve 36 sets the operating pressureof the system 10.

The gas-water mixture 24 is communicated to a degassing separator vessel32 for separation of the biogas lower solubility gas, for example,methane, from the gas-water mixture 24 to be conveyed to a gas-waterseparation device 34 that may be a pressure release valve that allowsscrubbed gas to exit the system 10. The high solubility gas-watermixture 28 is conveyed to a discharge pressure control valve 36 orbackpressure regulator that allows pressure release of the highsolubility gas-water mixture 28 to a drain 38 or a water return vessel40 for recycling.

The water return vessel 40 may have an overflow drain 38. A portion ofthe high solubility gas-water mixture 28 may be returned. The highsolubility gas-water mixture 28 return rates may be between 1 and 100percent of the water needed for operation of the venturi device 30. Thewater influent 22 may be between 1 and 100 percent of the water neededfor venturi device 30 operation. A percentage of the two water sourcesmay be merged to produce the total water influent for system 10operation. There may also be make-up water 44 influent to the waterreturn vessel 40 to maintain proper water flow and pressure conditionsin the system 10.

Example

The following experimental example illustrates the use of the method andsystem when practicing the invention. A pilot plant size, one inch,venturi injector was connected to a degas separator and the gas effluentwas controlled by a discharge pressure control valve. The highsolubility gas-water mixed effluent was controlled by a dischargebackpressure regulator and drained to a wastewater aeration basin. Thepilot system was installed at operating wastewater treatment facilitiesas an alternative to flaring the acid phase gas. The following Table 1illustrates the industry standard valves for biogas and the range andcomposition of the biogas tested.

TABLE 1 Component Typical Observed Methane (by deduction) 55-65% 30¹;50-65% Carbon Dioxide 35-45% 68¹; 32-39% Hydrogen Sulfide 1,500 ppm7,000¹; 150-8,000 ppm Water Saturated at 95° F. Saturated at 95° F.Pressure 2-12 in W.C.² 3-7 in W.C.² Note: ¹Acid phase gas sample: ²Unitsinches of water column

The Table 1 illustrates the differences in observed gas quality betweenpublished textbook values and the actual gas composition that wasmeasured.

The pilot system demonstration was based on the differential solubilityof the hydrogen sulfide and carbon dioxide to methane. Table 2 belowillustrates the solubility differences for the three gases in water.

TABLE 2 Compound Solubility¹ Difference Methane 4.11 N/A Carbon Dioxide300.27 730% Hydrogen Sulfide 256.01 640% Note: ¹Units are ft³ gas/1,000Gallons of water.

The pressurized water source was the wastewater treatment plant washwater/plant water system as the influent to the venturi device injectorinlet and the biogas was that produced at the treatment plant in ananaerobic process with the biogas influent connected to the vacuum orsuction port of the venturi device. The gas-water mixture effluent ofthe venturi device was then processed through the degas separator forthe cleaned gas, primarily methane, to be collected at the top of thedegas separator at a pressure release valve, and for the high solubilitygas-water mixture, primarily carbon dioxide and hydrogen sulfide inwater, to be drained through a discharge pressure control valve to adrain to aeration basins of the waste treatment plant. In theexperiments the pressure of the high solubility gas-water mixture 28after the discharge pressure control valve 36 was less than 5 psi. Thedegas separator used was a centrifugal vortex structure that separatesentrained gases from a liquid based on density differences between thegases and the liquid. Table 3 below illustrates results obtained fromthe pilot system testing.

TABLE 3 Component Inlet Outlet Methane (by deduction) 30¹; 50-65% 95-98%Carbon Dioxide 68¹; 32-39% <2% Hydrogen Sulfide 7,000¹; 150-8,000 <3 ppmWater Saturated at 95° F. Saturated at 65° F.² Pressure 3-7 in. W.C. 1.5psig Note: ¹Acid phase gas sample: ²Water cools gas removing moisture.

Methane has limited solubility in water; therefore, a mass balance wasdetermined to identify the amount of methane that might be lost to thewater in this process. Based on the solubility of methane presented inTable 2, less than 1.8 percent of the methane in the biogas treated bythe system should be lost to the water. This should make the system 98.2percent efficient in methane recovery. A full size gas scrubbing systemfor a typical wastewater treatment plant that may be capable of treating50 scfm of acid phase biogas may require a four inch venturi injectorand 350 gpm of water.

While the invention has been particularly shown and described withrespect to the illustrated embodiments thereof, it will be understood bythose skilled in the art that the foregoing and other changes in formand details may be made therein without departing from the spirit andscope of the invention.

We claim:
 1. A system for treating a biogas stream, comprising: a biogasstream source comprising a municipal wastewater treatment facility,wherein the biogas stream comprises methane, carbon dioxide, andsiloxanes and is produced from the anaerobic decomposition of organicmatter; an influent water source comprising the municipal wastewatertreatment facility; a venturi device in communication with the biogasstream source and the influent water source to combine the biogas streamand the influent water to produce a gas-water effluent; a degasseparator in communication with the venturi device for receipt of thegas-water effluent to produce a relatively low solubility gas effluentand a relatively high solubility gas-water mixture effluent; a gas-waterpressure release valve in communication with the degas separator tocontrol release of the relatively low solubility gas effluent; and adischarge pressure control valve in communication with the degasseparator to control release of the relatively high solubility gas-watermixture effluent.
 2. The system of claim 1, wherein the venturi devicehas an injector inlet for receipt of the influent water and aconstriction vacuum portion for receipt of the biogas stream.
 3. Thesystem of claim 1, wherein the degas separator is a centrifugal vortexstructure that separates entrained gases from a liquid based on densitydifferences between the gases and the liquid.
 4. The system of claim 1,further comprising a water return vessel in communication with thedischarge pressure control valve and the venturi device, wherein thewater return vessel returns at least a portion of the relatively highsolubility gas-water mixture effluent to the venturi device.
 5. Thesystem of claim 4, further comprising a pump to return the at least aportion of the relatively high solubility gas-water mixture effluent tothe venturi device.
 6. The system of claim 4, further comprising amakeup water source in communication with the water return vessel forproviding makeup water to the water return vessel.